Solution Hydrure de diisobutylaluminium, 1,0 M en heptane

Code: 214965-100ml D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Diisobutylaluminum hydride (DIBAL-H) is a common reducing agent to reduce aldehydes, ketones, esters, acids and acid chlorides to the corresponding alcohols. Some...


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Votre prix
£70.00 100ML
£84.00 inc. VAT

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Diisobutylaluminum hydride (DIBAL-H) is a common reducing agent to reduce aldehydes, ketones, esters, acids and acid chlorides to the corresponding alcohols. Some of the applications are:Synthesis of α-acetoxy ethers by reduction and subsequent acetylation of esters.Synthesis of coniferyl, sinapyl, and p-coumaryl alcohol by selective reduction of corresponding cinnamate esters.Reduction of secondary phosphine oxides (SPOs) to the corresponding phosphines.DIBAL-H can also be used in the hydroalumination of alkene and alkynes.

Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.

Packaging

100, 800 mL in Sure/Seal™

concentration1.0 M in heptane
density0.731 g/mL at 25 °C
formliquid
InChI keyAZWXAPCAJCYGIA-UHFFFAOYSA-N
InChI1S/2C4H9.Al.H/c2*1-4(2)3;;/h2*4H,1H2,2-3H3;;
Quality Level200
reaction suitabilityreagent type: reductant
SMILES stringCC(C)C[AlH]CC(C)C
Cas Number1191-15-7
Hazard Class4.2
Un Number3394
Pack GroupI
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