(R,R)-(-)-N,N-diméthyle - 1,2 - cyclohexanediamine, >=97,0% (GC)

Code: 671274-1g D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

(R,R)-(−)-N,N′-Dimethyl-1,2-cyclohexanediamine can be used:As a ligand in the preparation of 4H-benzo[f]imid...


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Votre prix
$416.15 1G
$499.38 inc. VAT

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

(R,R)-(−)-N,N′-Dimethyl-1,2-cyclohexanediamine can be used:As a ligand in the preparation of 4H-benzo[f]imidazo[1,4]diazepin-6-one through multi-component Ullmann coupling reaction.In one of the key synthetic steps for the preparation of tricyclic γ-secretase modulators.To prepare chiral fluorous diamino-diol proligand, which is used in the synthesis of zirconium metal complexes applicable as catalysts in 1-hexene polymerization.

General description

(R,R)-(-)-N,N′-Dimethyl-1,2-cyclohexanediamine is a N,N′-dimethylated derivative of enantiopure 1,2-diaminocyclohexane. It can be formed during the hydrolysis of (R3a,R7a)-1,3-(dimethyl)-2-phenyl-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3,2-benzodiazaphosphole 2-oxide using HCl-methanol.

Packaging

1 g in glass bottle

assay≥97.0% (GC)
InChI keyJRHPOFJADXHYBR-HTQZYQBOSA-N
InChI1S/C8H18N2/c1-9-7-5-3-4-6-8(7)10-2/h7-10H,3-6H2,1-2H3/t7-,8-/m1/s1
mp39-44 °C
optical activity[α]/D -145±5°, c = 4.47 in chloroform
SMILES stringCN[C@@H]1CCCC[C@H]1NC
storage temp.2-8°C
Cas Number68737-65-5
Hazard Class8
Un Number2735
Pack GroupII
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