(1S )-(+)-3 - carène,99 %

Code: 441619-1g D2-231

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Chiral building block for the preparation of bicyclo[3.2.0]heptenes that are useful intermediates in the synthesis of (+)-lineatin and both enantiomers of capnell...


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Votre prix
$64.38 1G
$77.26 inc. VAT

Non disponible en dehors du Royaume-Uni et de l'Irlande

Application

Chiral building block for the preparation of bicyclo[3.2.0]heptenes that are useful intermediates in the synthesis of (+)-lineatin and both enantiomers of capnellene. Has been converted to its corresponding allenyl allylic ether for studies of its thermal isomerization chemistry. Precursor to di(4-isocaranyl)borane, an asymmetric hydroboration reagent for olefins.

(1S)-(+)-3-Carene has been used as a standard during the quantification of components in Lavandula stoechas essential oils by fast gas chromatography-mass spectrometry (FGC-EI/MS). It may be used as a starting material in the total synthesis of (+)-ingenol. It may also be used to synthesize (1S,3S,4S,6R)-3,7,7-trimethyl-4-morpholino-4-yl-bicyclo(4.1.0)heptano-3-ol, which can catalyze the addition of diethylzinc to different aldehydes with high enantioselectivity.

General description

(1S)-(+)-3-Carene is a monoterpene.

Packaging

1, 5 g in glass bottle

assay99%
bp170-172 °C (lit.)
density0.865 g/mL at 25 °C (lit.)
formliquid
InChI keyBQOFWKZOCNGFEC-BDAKNGLRSA-N
InChI1S/C10H16/c1-7-4-5-8-9(6-7)10(8,2)3/h4,8-9H,5-6H2,1-3H3/t8-,9+/m1/s1
optical activity[α]20/D +17°, neat
Quality Level200
refractive indexn20/D 1.472 (lit.)
SMILES string[H][C@@]12CC=C(C)C[C@]1([H])C2(C)C
Code
Description
Unité de vente
Prix annoncé
Qté
441619-5G
Unité:5G
Prix annoncé: $236.35
Source:Prix annoncé
Cas Number498-15-7
Hazard Class3
Un Number2319
Pack GroupIII
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