Non disponible en dehors du Royaume-Uni et de l'Irlande
Application
Trifluoromethanesulfonic acid can be used as a catalyst to prepare: Substituted tetrahydrofurans and tetrahydropyrans by cyclization of corresponding unsaturated alcohols under acidic conditions. Nitriles from corresponding aldehydes by Schmidt reaction. Disubstituted five-membered ring lactones by allylboration reaction between 2-alkoxycarbonyl allylboronates and aldehydes. It can also be used as a catalyst in the Fischer glycosylation and Friedel-Crafts acylation reactions.
Deglycosylation agent
General description
Trifluoromethanesulfonic acid is a strong organic acid. It can be prepared by reacting bis(trifluoromethylthio)mercury with H2O2. On mixing with HNO3, it affords a nitrating reagent (a nitronium salt). This reagent is useful for the nitration of aromatic compounds. Its dissociation in various organic solvents has been studied.
Legal Information
ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC
Packaging
5, 25 g in ampule
100, 500 g in glass bottle
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