Triisopropylsilane, 99%

Code: 233781-10g D2-231

Not available outside of the UK & Ireland.

Application

Used in a highly diastereoelective preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbene complex.

The bulky isopropyl groups (v...


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$43.65 10G

Not available outside of the UK & Ireland.

Application

Used in a highly diastereoelective preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbene complex.

The bulky isopropyl groups (vs. ethyl) allow for more selective reductions, e.g., beta-selective reduction of anomeric C-phenyl ketals, but do not diminish their activity (e.g. in the copper triflate catalyzed reductive etherification of trimethylsilyl ethers).

assay98%
bp84-86 °C/35 mmHg (lit.)
density0.773 g/mL at 25 °C (lit.)
formliquid
InChI keyYDJXDYKQMRNUSA-UHFFFAOYSA-N
InChI1S/C9H22Si/c1-7(2)10(8(3)4)9(5)6/h7-10H,1-6H3
Quality Level200
reaction suitabilityreagent type: reductant
refractive indexn20/D 1.434 (lit.)
SMILES stringCC(C)[SiH](C(C)C)C(C)C
Code
Description
Unit Size
List Price
Qty
233781-250G
Unit:250G
List Price: $382.80
Source:List Price
ADD
233781-50G
Unit:50G
List Price: $85.26
Source:List Price
ADD
Cas Number6485-79-6
Hazard Class3
Un Number1993
Pack GroupIII
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