Diisobutylaluminum hydride solution, 1.0 M in hexanes

Code: 190306-100ml D2-231

Not available outside of the UK & Ireland.

Application

Diisobutylaluminum hydride solution (1.0 M in hexanes) can be used in the synthesis of potassium diisobutyl-t-butoxyaluminum hydride (PDBBA), a novel reducing age...


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Your Price
£59.60 100ML

Not available outside of the UK & Ireland.

Application

Diisobutylaluminum hydride solution (1.0 M in hexanes) can be used in the synthesis of potassium diisobutyl-t-butoxyaluminum hydride (PDBBA), a novel reducing agent for the chemoselective conversion of esters in the presence of nitriles. The DIBAL-triethylamine complex can reduce α-oxoketene dithioacetal to the saturated ketone.

Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.

General description

Diisobutylaluminum hydride reducing agent is commonly used for the reduction of an ester to aldehyde.

Packaging

100, 4×100, 800 mL in Sure/Seal™

concentration1.0 M in hexanes
density0.701 g/mL at 25 °C
formliquid
InChI keyAZWXAPCAJCYGIA-UHFFFAOYSA-N
InChI1S/2C4H9.Al.H/c2*1-4(2)3;;/h2*4H,1H2,2-3H3;;
Quality Level200
reaction suitabilityreagent type: reductant
SMILES stringCC(C)C[AlH]CC(C)C
Code
Description
Unit Size
List Price
Qty
190306-800ML
Unit:EACH
List Price: £294.00
Source:List Price
ADD
Cas Number1191-15-7
Hazard Class4.2
Un Number3394
Pack GroupI
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