tert-Butyl peracetate solution, 50 wt. % in odorless mineral spirits

Code: 388076-500ml D2-231

Not available outside of the UK & Ireland.

Application

Reagent used as a methyl-radical source under photoredox catalysis in conjunction with photocatalyst [Ir{dF(CF3)ppy}2(dtbpy)]PF6 ...


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$121.66 500ML
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Not available outside of the UK & Ireland.

Application

Reagent used as a methyl-radical source under photoredox catalysis in conjunction with photocatalyst [Ir{dF(CF3)ppy}2(dtbpy)]PF6 (Aldrich L511765) for late-stage functionalization of biologically active heterocycles.Late-Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis

Allows the direct copper catalyzed acetoxylation of β-lactams at the 4-position.

Packaging

500 mL in poly bottle

concentration50 wt. % in odorless mineral spirits
density0.828 g/mL at 25 °C
formliquid
InChI keySWAXTRYEYUTSAP-UHFFFAOYSA-N
InChI1S/C6H12O3/c1-5(7)8-9-6(2,3)4/h1-4H3
Quality Level100
reaction suitabilityreaction type: Photocatalysis, reagent type: catalyst
refractive indexn20/D 1.412
SMILES stringCC(=O)OOC(C)(C)C
t1/210 hr(101 °C, 0.2 M in benzene)
Cas Number107-71-1
Hazard Class5.2
Un Number3103
This product has met the following criteria: