Tetrapropylammonium perruthenate, 97%

Code: 330744-250mg D2-231

Not available outside of the UK & Ireland.

Application

Tetrapropylammonium perruthenate (TPAP) can be used as a catalyst: For the conversion of sulfides to sulfones by oxidation reaction. In the isomerization of all...


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Your Price
£78.70 250MG

Not available outside of the UK & Ireland.

Application

Tetrapropylammonium perruthenate (TPAP) can be used as a catalyst: For the conversion of sulfides to sulfones by oxidation reaction. In the isomerization of allylic alcohols into the corresponding saturated carbonyl derivatives.Along with N-methylmorpholine N-oxide (NMO) for the cleavage of glycol to carboxylic acids.TPAP can also be used as an oxidizing reagent:For the oxidation of benzyl alcohol to benzaldehyde and steroidal alcohols to corresponding ketones.To convert N,N′-dihydroxyimidazolidines to nitronyl nitroxide free radicals. To oxidize hydroxyl-substituted tri-n-butylammonium trifluoroborates to aldehydes and ketones without concomitant cleavage of the carbon-boron bond.

General description

Tetrapropylammonium perruthenate is a mild oxidizing agent used for the oxidation of alcohols to corresponding carbonyl compounds. It is a non-volatile, air-stable, and readily soluble reagent, which can be used either stoichiometrically or catalytically with a suitable co-oxidant.

Packaging

1 g in glass bottle

250 mg in glass bottle

assay97%
formsolid
InChI keyNQSIKKSFBQCBSI-UHFFFAOYSA-N
InChI1S/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;
mp~160 °C (dec.) (lit.)
Quality Level200
reaction suitabilityreagent type: oxidant
SMILES string[O-][Ru](=O)(=O)=O.CCC[N+](CCC)(CCC)CCC
Code
Description
Unit Size
List Price
Qty
330744-1G
Unit:1G
List Price: £133.00
Source:List Price
ADD
Cas Number114615-82-6
Hazard Class5.1
Un Number1479
Pack GroupII
This product has met the following criteria: