(S,S)-(-)-Hydrobenzoin, 99%, optical purity ee: 99% (GLC)

Code: 256269-5g D2-231

Not available outside of the UK & Ireland.

Application

(S,S)-(-)-Hydrobenzoin may also be used to prepare (1S,2S,1′S)- and (1S,2S,1′R)-2-(cyclohex-2′-enyl...


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Your Price
$156.60 5G
$187.92 inc. VAT

Not available outside of the UK & Ireland.

Application

(S,S)-(-)-Hydrobenzoin may also be used to prepare (1S,2S,1′S)- and (1S,2S,1′R)-2-(cyclohex-2′-enyloxy)-1,2-diphenylethanol, which are intermediates to prepare enantiopure cyclohexitols. The (S,S)-(-)-hydrobenzoin/Ca complex may be used to catalyze the direct asymmetric aldol reaction of acetophenone and pivalaldehyde to form (R)-3-hydroxy-4,4-dimethyl-1-phenylpentan-1-one.

C2 symmetric chiral diol with versatile applications as a chiral auxiliary, building block, and chiral ligand.

General description

Chiral reagent.

Other Notes

Tandem Mass Spectrometry data independently generated by Scripps Center for Metabolomics is available to view or download in PDF. 256269.pdf Tested metabolites are featured on Scripps Center for Metabolomics METLIN Metabolite Database. To learn more, visit sigma.com/metlin.

Packaging

5, 25 g in glass bottle

assay99%
InChI keyIHPDTPWNFBQHEB-KBPBESRZSA-N
InChI1S/C14H14O2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-16H/t13-,14-/m0/s1
mp148-150 °C (lit.)
optical activity[α]24/D −94°, c = 2.5 in ethanol
optical purityee: 99% (GLC)
SMILES stringO[C@H]([C@@H](O)c1ccccc1)c2ccccc2
Code
Description
Unit Size
List Price
Qty
256269-25G
Unit:25G
List Price: $636.55
Source:List Price
ADD
Cas Number2325-10-2
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