Copper(I) trifluoromethanesulfonate benzene complex, technical grade, 90%

Code: 407240-5g D2-231

Not available outside of the UK & Ireland.

Application

Copper(I) trifluoromethanesulfonate benzene complex can be used as a catalyst: To synthesize enol-esters via copper(I) carboxylate intermediate formation. In the ...


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Your Price
$256.65 5G

Not available outside of the UK & Ireland.

Application

Copper(I) trifluoromethanesulfonate benzene complex can be used as a catalyst: To synthesize enol-esters via copper(I) carboxylate intermediate formation. In the enantioselective allylic oxidation of cyclic alkenes. To prepare 2,5-disubstituted pyrrolidine derivatives from N-alkenyl, alkynyl and alkyl N-benzoyloxysulfonamides via the sulfonamidyl radical formation. It can also be used in combination with amino acid-based chiral phosphine ligands to catalyze asymmetric conjugate additions of alkylzincs to acyclic α,β-unsaturated ketones, affording β-alkylcarbonyls in high yield and with excellent enantioselectivity.

Packaging

1, 5 g in glass bottle

assay90%
formpowder
gradetechnical grade
InChI keyGNXZWVVAAMVOJY-UHFFFAOYSA-L
InChI1S/C6H6.2CHF3O3S.2Cu/c1-2-4-6-5-3-1;2*2-1(3,4)8(5,6)7;;/h1-6H;2*(H,5,6,7);;/q;;;2*+1/p-2
mp160 °C (dec.) (lit.)
Quality Level100
reaction suitabilitycore: copper, reagent type: catalyst
SMILES string[Cu+].[Cu+].c1ccccc1.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
Cas Number42152-46-5
Hazard Class4.1
Un Number3175
Pack Group2
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