-(-)-alpha-Methoxy-alpha-(trifluoromethyl)phenylacetyl chloride,;, for chiral derivatization, >=99.0%

Code: 65363-100mg D2-231

Not available outside of the UK & Ireland.

Application

It was used for derivatizing D-arabinitol and L-arabinitol samples for high performance thin layer chromatography (HPTLC) analysis for studying resolution of the ...


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$110.64 100MG
$132.77 inc. VAT

Not available outside of the UK & Ireland.

Application

It was used for derivatizing D-arabinitol and L-arabinitol samples for high performance thin layer chromatography (HPTLC) analysis for studying resolution of the diastereoisomer.

Ready-to-use reagent for the determination of the enantiomeric purity of alcohols and amines after derivatization; doi:10.1038/nprot.2007.354

General description

(R)-(-)-a-Methoxy-a-(trifluoromethyl)phenylacetyl chloride (Mosher’;s acid chloride) is generally used as a chiral derivatizing agent. It is easily available in enantiomerically pure form. It can form diastereomers with both alcohols and amines.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

ChiraSelect is a trademark of Sigma-Aldrich Co. LLC

Other Notes

Please note that R(-)-MTPA-Cl is derived from S(-)-MTPA

Packaging

100, 500 mg in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

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assay≥99.0%, ≥99.0% (AT)
bp213-214 °C (lit.)
density1.35 g/mL at 25 °C (lit.)
gradefor chiral derivatization
InChI keyPAORVUMOXXAMPL-VIFPVBQESA-N
InChI1S/C10H8ClF3O2/c1-16-9(8(11)15,10(12,13)14)7-5-3-2-4-6-7/h2-6H,1H3/t9-/m0/s1
optical activity[α]20/D −137±2°, c = 6.4% in carbon tetrachloride
optical purityenantiomeric ratio: ≥99.5:0.5 (GC)
product lineChiraSelect
Quality Level100
qualityLiChropur
refractive indexn20/D 1.47 (lit.), n20/D 1.469
shipped inwet ice
SMILES stringCO[C@](C(Cl)=O)(c1ccccc1)C(F)(F)F
storage temp.−20°C
technique(s)HPLC: suitable
Code
Description
Unit Size
List Price
Qty
Cas Number39637-99-5
Hazard Class8
Un Number3265
Pack GroupII
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