(-)-Ipc2B(allyl)borane solution, 1 M in pentane

Code: 678538-5ml D2-231

Not available outside of the UK & Ireland.

Application

This allylboration reagent is a convenient, salt-free, stable solution of a chiral allyl borane for asymmetric allylation of aldehydes leading to chiral homoallyl...

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$82.04 5ML

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OVERVIEW

Not available outside of the UK & Ireland.

Application

This allylboration reagent is a convenient, salt-free, stable solution of a chiral allyl borane for asymmetric allylation of aldehydes leading to chiral homoallylic alcohols.

Other Notes

Material may become hazy upon cooler storage, this will not affect use

Under refrigerator storage, these salt-free, Ipc₂B(allyl) reagents do not show any appreciable decrease in selectivity is observed after several months. They exhibit excellent reactivity and reactions can be performed at 5°C, even in water.

Packaging

5, 25 mL in ampule

SPECIFICATIONS

bp	35-36 °C
concentration	1 M in pentane
density	0.638 g/mL at 25 °C
InChI key	ZIXZBDJFGUIKJS-RLEROFIGSA-N
InChI	1S/C23H39B/c1-8-9-24(20-12-16-10-18(14(20)2)22(16,4)5)21-13-17-11-19(15(21)3)23(17,6)7/h8,14-21H,1,9-13H2,2-7H3/t14-,15-,16+,17+,18-,19-,20-,21-/m1/s1
optical activity	[α]20/D −35 to ±5°, c = 1
Quality Level	100
SMILES string	C[C@H]1[C@@H](C[C@@H]2C[C@H]1C2(C)C)B(CC=C)[C@@H]3C[C@@H]4C[C@H]([C@H]3C)C4(C)C
storage temp.	−20°C