Tris(triethylsilyl)silane,

Code: 736856-5g D2-231

Not available outside of the UK & Ireland.

Application

Tris(triethylsilyl)silane can be used as a hydrogen atom donor reagent in chemical synthesis due to its weak Si-H bond. Hydrogen abstraction from tris(triethylsil...


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Your Price
$245.67 5G
$294.80 inc. VAT

Not available outside of the UK & Ireland.

Application

Tris(triethylsilyl)silane can be used as a hydrogen atom donor reagent in chemical synthesis due to its weak Si-H bond. Hydrogen abstraction from tris(triethylsilyl)silane yields a highly stable silyl radical.It can be used as a reagent: In the radical coupling reaction to generate C-C bonds from alkyl-halogen compounds using iridium and nickel catalysts. To synthesize α-arylated product via cross-electrophile coupling reaction between α-chloro carbonyl and aryl bromide in the presence of nickel and iridium catalysts.

Tris(triethylsilyl)silane can be incorporated as a directing group for various regio- and stereo-selective reactions. Hydrogen abstraction from tris(triethylsilyl)silane yields highly stable silyl radical.

Packaging

5 g in glass bottle

density0.887 g/mL at 25 °C
formliquid
InChI keyWNGZMQFMMHZKBG-UHFFFAOYSA-N
InChI1S/C18H46Si4/c1-10-20(11-2,12-3)19(21(13-4,14-5)15-6)22(16-7,17-8)18-9/h19H,10-18H2,1-9H3
Quality Level100
reaction suitabilityreagent type: reductant
refractive indexn20/D 1.526
SMILES stringCC[Si](CC)(CC)[SiH]([Si](CC)(CC)CC)[Si](CC)(CC)CC
storage temp.2-8°C
Cas Number0025436-74-2
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